Chutti TV Tamil Youtube Official Channel. Chutti TV Tamil Youtube Official Channel. Home; Cinema. Cinema Video; Movie Review; Cinema News; Cinema Interviews. Sun. Network - Channel Deatils. CHUTTI TVChutti TV - All Time Favorite Kids Channel in Tamil. All in all Azhaghu Raja. Mon- Sun. 1. 0: 0. PMMore Programs: Select. All in all Azhaghu Raja. Animated Movie. Anna's Tales. Boots, Backpack, Map and Swiper help their friend Dora on her adventures as they sing, dance and learn in Spanish. Go on everyday adventures with Dora when you watch full episodes and video clips. Sing songs and dance along to music videos from the show that teach both spanish and. Chutti TV - All Time Favorite Kids Channel in Tamil. All in all Azhaghu Raja Mon-Sun, 10:00 PM. Balaveear. Cakes and Candles. Care Bears. Care Bears & Cousins. Chutti Seithigal. Dragon Booster. Fillers. Gee Boom Boy- Super Buffalo. George of the Jungle. Godzilla. Heidi. Jackie Chan. Jumanji. Kate & Mim Mim. Lassie. Lion Kings Timon & Pumbaa. Mad Stuff with Rob. Magic Tiger. Penguins of Madagascar. Reel a Real a. Shakalaka Magic Slate. Spectacular Spiderman. Stuart Little. Stuart. Little. The Adventures of Nano Boy. The New Adventure Of Hanuman. Tree Fu Tom. Ulaga Sirukadhaigal. Varuthapadatha Karadi Sangam. Dora the Explorer ( Crank Dat Soulja Boy).
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DPerugia. COME RAGGIUNGERCIIN AUTO. Situato comodamente nella prima periferia della citt. Programmazione completa del cinema Uci Cinemas Ancona di Ancona, Via Pietro Filonzi, 4 - Ancona. Telefono: +39 892960 (no prefisso). Consultabile gratuitamente online. Programmazione completa del cinema Uci Cinemas Jesi di Jesi, Via Marco Polo, 5 - Jesi (Ancona). Telefono: +39 892960 (no prefisso). Consultabile gratuitamente online. Welcome to the Super Sentai guide at TV.com. Since 1975, the Super Sentai series has become a staple in Japanese society. Super Sentai was used as the source material. Super Sentai - Show News, Reviews, Recaps and Photos. Welcome to the Super Sentai guide at TV. Since 1. 97. 5, the Super Sentai series has become a staple in Japanese society. Super Sentai was used as the source material for what is known in America as Power Rangers starting in 1. Zyu. Ranger and currently up to Zyuden Sentai Kyoryuger. Gokaiger marked the 3. Super Sentai in Japan.
The following is a full list of past and present Sentai seasons: - Himitsu Sentai Go. Ranger (Secret Squadron Five Ranger), Aired from 1. J. A. K. Q. Dengekitai (J. A. K. Q. Blitzkrieg Squad) Aired in 1. Battle Fever JAired in 1. Denshi Sentai Denjiman (Electronic Squadron Denjiman) Aired in 1. Taiyou Sentai Sun Vulcan (Solar Squadron Sun Vulcan) Aired in 1. Dai Sentai Goggle V (Great Squadron Goggle Five) Aired in 1. Kagaku Sentai Dynaman (Science Squadron Dynaman) Aired in 1. Choudenshi Bioman (Super Electronic Bioman) Aired in 1. Dengeki Sentai Changeman (Blitzkrieg Squadron Changeman) Aired in 1. Choushinsei Flashman (Supernova Flashman) Aired in 1. Hikari Sentai Maskman (Light Squadron Maskman) Aired in 1. Choujuu Sentai Liveman (Super- Beast Squadron Liveman) Aired in 1. Kousoku Sentai Turbo. Ranger (High- Speed Squadron Turbo Ranger) Aired in 1. Choujuu Sentai Liveman (Chikyuu Sentai Fiveman (Earth Squadron Fiveman) Aired in 1. Choujin Sentai Jetman (Birdman Squadron Jetman) Aired in 1. Kyouryuu Sentai Zyu. Ranger (Dinosaur Squadron Beast Ranger) Aired in 1. Gosei Sentai Dai. Ranger (Five- Star Squadron Great Ranger) Aired in 1. Ninja Sentai Kaku. Ranger (Ninja Squadron Hidden Ranger) Aired in 1. Chouriki Sentai Oh. Ranger (Super- Power Squadron Overtech Hardware Ranger) Aired in 1. Gekisou Sentai Car. Ranger (Racing Squadron Car Ranger) Aired in 1. Seijuu Sentai Gingaman (Star- Beast Squadron Milky Way Man) Aired in 1. Kyuukyuu Sentai Go. Go- V (Rescue Squadron Go. Go V) Aired in 1. Mirai Sentai Time. Ranger (Future Squadron Time Ranger) Aired in 2. Hyakujuu Sentai Gao. Ranger (1. 00 Beast Squadron Growl Ranger) Aired in 2. Ninpuu Sentai Hurricanger (Stealth- Wind Squadron Hurricane Ranger) Aired in 2. Bakuryuu Sentai Aba. Ranger (Blastasaur Squadron Outburst Ranger) Aired in 2. Tokusou Sentai Deka. Ranger (Special Investigation Squadron Detective Ranger) Aired in 2. Mahou Sentai Magi. Ranger (Magic Squadron Magic Ranger) Aired in 2. Go. Go Sentai Boukenger (Rumbling Squadron Adventure Ranger) Aired in 2. J. 4. 9 episodes.- Engine Sentai Go- Onger (Engine Squadron Go- On Ranger) Aired in 2. Samurai Sentai Shinkenger (Samurai Squadron Shinkenger) Aired in 2. Tensou Sentai Goseiger (Heavenly Armament Squadron Goseiger) Aired in 2. Kaizoku Sentai Gokaiger (Pirate Squadron Ranger) Aired in 2. Tokumei Sentai Go- Busters (Special Mission Squadron Go- Busters) Aired in 2. Zyuden Sentai Kyoryuger (Electrobeast Squadron Dinosaurger)Aired in 2. Ressha Sentai To. Qger (Train Squadron Limited Express Ranger)Aired in 2. Shuriken Sentai Ninninger (Shuriken Squadron Ninninger)Aired in 2. Doubutsu Sentai Zyuohger (Animal Squadron Beast King Ranger)Aired in 2. Uchu Sentai Kyuranger (Space Squadron Kyuranger, Space Squadron Nine Ranger)Coming in 2. Movies: Richard Linklater shares his alternate 80s soundtrack for Fast And 7 Furious Full Movie8/29/2017 We ride the Fast And Furious series from B- movie start to A- list finish. With Run The Series, The A. V. Club examines film franchises, studying how they change and evolve with each new installment. The summer of 2. 00. There were follow- ups to Rush Hour, The Mummy, and American Pie; even Jurassic Park III did well. In addition, many of that summer’s non- sequels became part ones later, spawning additional installments that range from massive successes (the Shrek franchise) to footnotes (Legally Blonde 2: Red, White, And Blonde). Yet 1. 4 years later, most of these series have long since ended. After long delays, The Mummy and Rush Hour managed one more sequel apiece, while Jurassic Park went into a decade- plus hibernation of development. Shrekmania subsided by 2. Planet Of The Apes, which Fox hoped to jump- start as a new series in 2. Somehow, the last man standing from the summer of 2. Vin Diesel. The Fast And The Furious was a big hit, but it didn’t seem at the time like a franchise play. If anything, it felt like counterprogramming to the season’s trendier blockbusters. Rather than movie stars or cutting edge effects, it relied on a spirited if clich. As with many less sequel- ready hits, The Fast And The Furious spawned one anyway; no one seemed particularly surprised to see a lackluster follow- up two years later with only one major member of the original cast. That The Fast And The Furious led into one of the longest- running continuous series in movies today, though, defied expectations—as did its creative surge right around the time that most series Tokyo Drift themselves into brick walls. Furious 7, the most recent installment, isn’t just the highest- grossing movie of the series; it’s also the highest- grossing and best- reviewed part seven ever outside of the Harry Potter dynasty. Though the seventh film draws the saga to a close in certain ways, an eighth film is assured, and at this point, a ninth and a 1. In its current incarnation, the Fast And Furious series essentially fulfills the promise of Sylvester Stallone’s Expendables movies, only without as much half- assed winking at itself. This is where action fans go to see what it would be like if Dwayne “The Rock” Johnson fought Jason Statham, or to watch Michelle Rodriguez square off against Gina Carano, or to speculate about what it might look like if Vin Diesel and The Rock conducted a semi- clandestine sexual affair (that last one requires some extrapolation outside the text of the movies, though not that much). Unlike the Expendables movies and any number of big, disappointing action pictures, these fantasy match- ups are supported, at least in the later films, by well- choreographed and satisfying set pieces. But it took some work to get the point where a drag- race franchise is now known for its standard- setting action scenes. The Fast And The Furious contains only one really elaborate set piece, a late- movie truck robbery that feels like a miniature version of the hood- leaping, body- dangling decathlons engineered by the later movies. Watch Fast and Furious 8 Online. The Fate of the Furious, release date, Trailer, Reviews, cast, Vin Diesel, Fast 8, Full Movie watch online, download, free. With Run The Series, The A.V. Club examines film franchises, studying how they change and evolve with each new installment.The summer of 2001 was a big season for. Most of the rest is an enjoyable m. The soundtrack in particular bumps with a jumpy mixture of musical detritus, including a remix of Limp Bizkit’s “Rollin’” and a lot of Ja Rule, who also co- starred. Hey boys, here is the next part of this movie(FAST AND FURIOUS 8 FULL MOVIE 2017) with. The video for 'See You Again', the Wiz Khalifa and Charlie Puth song featured in Furious 7, is now the most-streamed video of all time on YouTube. Superheroes, swimsuits, and special operatives await you in our Summer Movie Guide. Plan your season and take note of the hotly anticipated indie, foreign, and. Watch Fast and Furious 8 full movie online, download, HD for free. Fast and Furious 8 is a 2017 American action film directed by F. Beyond the verbal references to quarter- miles (the amount of time/distance by which Dom lives his life), Corona (Dom’s beer of choice), and family (a deceptively important concept for a gang of street- racers), The Fast And The Furious establishes the series- long relationship between Dom and Brian. They aren’t really buddy- buddy until the end of the fourth movie, but their bond begins in the first, with Walker playing the part of the moony- eyed little brother, alternately stepping to and beaming with admiration at the charismatic bruiser with the pavement- scrape voice. Throughout the series, Brian’s love of Dom feels subsumed in his supposed desire for Mia (Jordana Brewster), Dom’s more responsible sister, who eventually gets pregnant with Brian. Even the first film, which centralizes Mia like none of the others, ends on a moment of restrained passion between Brian and Dom, not Brian and Mia. That ending of the first film, where Brian gives Dom a head start rather than arresting him for his crimes, cements such a strong connection between the pair that the first two sequels achingly lack. Walker rolls into 2 Fast 2 Furious like a returning hero, reaching peak bro- ness early and often, not least because of the movie’s vast array of uttering and pronunciation of the word “bro” (including “bro,” “bruh,” and “bray”). But Brian’s childhood buddy Roman (Tyrese Gibson) proves a less- than- satisfying replacement for Dom—and his awareness of this provides one of the movie’s most entertaining through- lines, where Roman treats Brian not as an estranged friend returning to their old stomping ground but as a lover who once spurned him, eager to love- wrestle him to the ground in revenge. The pair’s bro- tastic homoeroticism, intentional or not, sets the movie apart from its predecessor, and sets a pattern of homoerotic subtext that future entries would echo but not equal. Otherwise, 2 Fast is just another amusingly dumb cop action movie with breaking- news exposition like, “Unfortunately, the cartels have been successful in getting drugs into Miami.” Any reminders, however superficial, of Miami Vice make a kind of time- warped sense; 2 Fast 2 Furious is basically an ’8.
Style- wise, director John Singleton traffics in tight close- ups of racers’ darting eyes and plenty of computer- assisted zooms between cars in lieu of cuts (some of which weirdly, and not particularly skillfully, suggest the visual invention of the Wachowskis’ Speed Racer). Also: shots of butts. The Fast And The Furious has scantily clad women hanging out at the races, especially in the desert- set and unfortunately named Race Wars expo, but 2 Fast 2 Furious really ups the ante, butts- wise, perhaps unmatched until James Wan uses them as kind of an audience pacifier in Furious 7. Don’t worry, the most recent sequel reassures: The director may have changed and Paul Walker may be about to leave, but these movies still take place in an extremely butt- centric universe. Singleton does a great job of making Rob Cohen, director of Stealth and The Skulls, seem like an elegant classicist, but both of them keep that universe relatively grounded—cop- movie stupid and ridiculous, not action- movie stupid and ridiculous. The upgrade in the quality of the franchise’s ridiculousness, and the gear shift into the modern action- adventure genre, was supervised by Justin Lin, who steered the series out of a Tokyo Drift dead- end, then leapt off the hood of the car after Fast And Furious 6. The Fast and the Furious (also known as Fast & Furious) is an American franchise based on a series of action films that is largely concerned with illegal street. Though some The Fast And The Furious: Tokyo Driftcultists inexplicably insist that it’s the best of the series, in retrospect it’s clearly a practice course for Lin, a kind of Fast And Furious Junior that’s ultimately (and not excitingly) about some high- school kids who know some guys in the Yakuza. Tokyo Drift in particular fudges some of its big moments: The climactic race takes place under cover of indistinct darkness, and Lin repeatedly uses point- of- view cheats when he sends his cars screeching around hairpin turns. Lin opens Fast & Furious, the fourth movie and the first reunion of the first movie’s core players, with a crackerjack truck heist, inching toward what the series would become, but its uneasy special- effects balancing of real metal with pixelated explosions mutes the impact of its chases through a mountain tunnel. By the time Fast Five picks up exactly where the previous movie leaves off, though, Lin really has it down; its first major action sequence (following an abbreviated assault on a prison bus) involves a train and multiple cars, one of which soars off a cliff as Dom and Brian redefine the terms of a survivable nick- of- time escape. It’s worth noting that Lin should not be mistaken for a formalist just because his cutting isn’t quite as fast or furious as some of his generational counterparts. A quick look at two arthouse action movies that came out within a year of Fast Five, Drive and Haywire, reveals what a genuinely stripped- down, old- school approach to the genre might look like. But in the realm of big- budget action sequences, which so often splatter CG detritus all over the screen, Lin’s set pieces arrange their moving parts with a quick, scannable rhythm. They also inject moments of credibility, however fleeting, into the giddy rush of blockbuster filmmaking. From the moment the car launches off a cliff in Fast Five, the series yearns to turn automobiles into flying machines, from the one that bursts through the front of an airplane in Fast And Furious 6to the one that jumps between skyscrapers in the centerpiece of Furious 7 (accompanied by a clever reference to Brian’s casual, playful admonishment to his young son earlier in the film, throwing his toys: “Cars don’t fly!”). Rather than a simple quarter- mile of makeshift urban racetrack or maybe a pardon for his youthful crimes, Dom seems to crave temporary absolution from the laws of gravity. This pursuit of weightlessness sometimes works ever so slightly against the sixth and seventh movies, which must rely on less practical stuntwork than Fast Five. The fifth film’s climactic heist/chase sequence, wherein two cars drag a gigantic safe through Rio, sets a series standard for destruction with real weight behind it, even if computers must have been used to enhance said destruction. The otherwise delightful airport climax of Furious 6 isn’t so convincing, even setting aside the dozens of miles of runway required for planes and cars to speed straightaway for 1. But if the car stunts in later movies soar beyond the limits of even mild plausibility, practicality gets a workout with the movie’s addition of fight scenes—basically a nonentity in the first four. Fast And Furious 5 (Full Movie) - MO Fast Five: Former cop Brian O'Conner partners with ex- con Dom Toretto on the opposite side of the law. Since Brian and Mia Toretto broke Dom out of custody, they've blown across many borders to elude authorities. Now backed into a corner in Rio de Janeiro, they must pull one last job in order to gain their freedom. As they assemble their elite team of top racers, the unlikely allies know their only shot of getting out for good means confronting the corrupt businessman who wants them dead. But he's not the only one on their tail. Hard- nosed federal agent Luke Hobbs never misses his target. When he is assigned to track down Dom and Brian, he and his strike team launch an all- out assault to capture them. But as his men tear through Brazil, Hobbs learns he can't separate the good guys from the bad. Now, he must rely on his instincts to corner his prey.. The Fate of the Furious. A apply of Fast and Furious 8 will be on unmask at the Salem Super Cruise when Mongoose Motorsports brings a 1. Corvette Grand Sport gasser on June 1. The 1. 2th occasional Super Cruise will be held June 8- 1. The aqua- blue Corvette, off the rack at the company’s 3. Ravenna, has a small change object in the latest Fast and Furious movie, Mongoose Motorsports co- owner Gary Krause said.“The Fate of the Furious,” by the same token known as Fast and Furious 8, is currently playing, for all that the gang up with built a abode of cars for “Fast and Furious 5” when it impoverished directed toward the movie trade in a essentially bigger style, Krause said. He and his mother, Tricia, arrest Mongoose Motorsports which builds and sells 1. Corvette Grand Sport replicas at the hand of a licensing agreement mutually General Motors Corp., mechanic of the Corvette. Mongoose Motorsports was put up into the movies in a noteworthy way and its website takes conclude notice of at which point it bankrupt in.“In the rollick of 2. The definition on the contrasting do of the phone asked us if we could cause to be all of our Grand Sport roadsters for a masterpiece motion picture.“We were as a result of given the shot to annex a part of the Fast and Furious pickup family. With thick thought and at some future timetually smaller timeline we accepted. It was a vital opportunity and an ultimately greater contest but it was the Fast and Furious right?”The work befriend ordered nine cars.“And so it began, the jumping off point was reside, and we en route building frames and bodies.“As cars came mutually we sent them mistaken to the production company. Everything was kept literally quiet, this was in working order to be a carrying a lot of weight blockbuster and we were mended to permeate of it.”Nine tailor- made cars were sent by mail and the silver Corvette roadster starred in a having a good hook “airborne” parade and it “ended up jumping inaccurate of a entitle, bouncing adjacent the dose of a well known own medicine and rapid off into a ravine. Dragon Ball Super - Cast Images. Voice Directors: Christopher Sabat, Rawly Pickens. US Premiere: Jan 0. US Conclusion: Ongoing. Japan Premiere: Jul 0. Japan Conclusion: Ongoing. Seasons: 1. Episodes: 6. 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Franchise: Dragon Ball. Characters on BTVA: 9. Watch Rance 0. 1: Hikari o Motomete The Animation Episode 1 . Rance 0. 1: Hikari o Motomete The Animation Episode 1 is from the hentai series Rance 0. Hikari o Motomete The Animation. If you enjoyed Rance 0. Hikari o Motomete The Animation Episode 1 please share it with your friends! Note that this video is hosted on a third- party video sharing website, and not affiliated with Hentai. Stigma or it's server. READ FAQ BEFORE COMMENTING(OR YOUR POST WILL BE DELETED)If you can't get pass Anti- Spam then just sign up here and you should be able to comment. Watch Latest Episode Added English Dub & Subbed Online! No spamming - this includes messages (pictures/videos) being posted 3+ times. It also includes gibberish (ex: dhsuiahduihasuhduashd) a. No flooding - Flooding is = 4+ posts in a row uninterrupted. Giant posts that take up a decent portion of the chat (otherwise known as a wall of text). And finally posts posted rapidly to the point that any conversations that may currently be going on is disrupted. No racism, sexism, any form of discrimination is prohibited. Even if it is a joke - not everyone is going to see it from the same point of view and someone will get offended one way or another. Legible text only (includes text and backgrounds); The chat is white, so please avoid using light colors unless you have a dark background to make it visible! No excessive caps. Some caps is okay, like using caps for emphasis or a couple smaller posts of caps (a. Constant caps is annoying, and is seen as yelling. Stream. Anime has a 0 porn tolerance. This means do not post or link the porn. You may be banned on sight. Find album reviews, stream songs, credits and award information for P.S. I Love You HBO's official website contains schedule information, original video content, episode guides, polls, bulletin boards, and more! Film Genre: Melodrama Comedy. Budget: $ 5. 0 million. Country of Origin: United States. Year of Release: 2. Director: Screenwriter: Operator: Somposer: Actors: Julianne Moore, Emma.
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The Shark Tank Season 1 full episode guide offers a synopsis for every episode in case you a missed a show. Browse the list of episode titles to find summary recap.HBO’s international streaming services HBO Nordic and HBO España accidentally published next week’s episode of Game of Thrones yesterday, and right now the ep is. The series starts when Phoebe Halliwell (Alyssa Milano) returns from New York and moves back into the family's Halliwell Manor in San Francisco to live with her. TV series. These can be watched on your computer, Apple TV or i. Pod with video. Click on the grey i. Tunes button to launch i. Tunes and see the free episode. Drama US – Drop Dead Divas – Back from the Dead – Comedy US – Grojband – Cloudy With a Change of Malt Balls – Kids US – Twisted – Pilot – Drama US – Shipping Wars – Monkey Business – Reality TV US – How It’s Made: Dream Cars – Morgan Aero Coupe – Nonfiction US – Doctor Who – The Impossible Astronaut – Sci- Fi/Fantasy US – Inside Men – Episode 1 – Drama US – Ancient Aliens – The Mayan Conspiracy – Nonfiction US – Top Shot – Sweating Bullets – Reality TV US – Ice Road Truckers – Aces and Jokers – Reality TV US – Mountain Men – Winter Is Coming – Reality TV US – Modern Marvels – Mega Speed Countdown – Nonfiction US – Necessary Roughness – Ch- Ch- Changes – Drama US – Bizarre Foods America – Washington DC – Nonfiction US – Misfits – Episode 1 – Drama US – Sesame Street – There’s an App for That – Kids US – The Real Story – Star Trek – Nonfiction US – The Exes – Toy Story – Comedy US – Airport 2. 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Play, streaming, watch and download Lihat Nih,, Digoyang Gempa 6,4 SR, Ternyata Aceh Sempat Ricuh video (01:50), you can convert to mp4, 3gp, m4a for free. Sir I m also a sportsman. And you are the promoters sir. I m a Weight-lifter. Sir this is a humble request that you can promote our Game i.e. Laminate floors need to be cleaned regularly in order to prevent them from getting scratched or warped, but using harsh. Tahun 1976, Steve Jobs, Steve Wozniak dan Ronald Wayne, dengan pendanaan dari manajer pemasaran produk dan teknisi semi-pensiun Intel A.C. TV news Liputan6, kumpulan video berita Liputan6 SCTV, meliputi beragam video berita Liputan6 Pagi, Liputan6 Siang, Liputan6 Petang, Liputan6 Malam. Epoxy - Wikipedia. This article is about the thermoset plastic materials. For the chemical group, see epoxide. Epoxy resins may be reacted (cross- linked) either with themselves through catalytic homopolymerisation, or with a wide range of co- reactants including polyfunctional amines, acids (and acid anhydrides), phenols, alcohols and thiols. These co- reactants are often referred to as hardeners or curatives, and the cross- linking reaction is commonly referred to as curing. Reaction of polyepoxides with themselves or with polyfunctional hardeners forms a thermosettingpolymer, often with high mechanical properties, temperature and chemical resistance. Epoxy has a wide range of applications, including metal coatings, use in electronics / electrical components/LED, high tension electrical insulators, paint brushes manufacturing, fiber- reinforced plastic materials and structural adhesives. Epoxy resin. The triamine hardener is shown in red, the resin in black. The resin's epoxide groups have reacted with the hardener and are not present anymore. The material is highly crosslinked and contains many OH groups, which confer adhesive properties. Epoxy resins are low molecular weight pre- polymers or higher molecular weight polymers which normally contain at least two epoxide groups. The epoxide group is also sometimes referred to as a glycidyl or oxirane group. A wide range of epoxy resins are produced industrially. The raw materials for epoxy resin production are today largely petroleum derived, although some plant derived sources are now becoming commercially available (e. High purity grades can be produced for certain applications, e. One downside of high purity liquid grades is their tendency to form crystalline solids due to their highly regular structure, which require melting to enable processing. An important criterion for epoxy resins is the epoxide content. This is commonly expressed as the epoxy equivalent weight, which is the number of epoxide equivalents in 1 kg of resin (Eq./kg), or as the equivalent weight, which is the weight in grammes of resin containing 1 mole equivalent of epoxide (g/mol). One measure may be simply converted to another: Equivalent weight (g/mol) = 1. Eq./kg)The equivalent weight or epoxide number is used to calculate the amount of co- reactant (hardener) to use when curing epoxy resins. Epoxies are typically cured with stoichiometric or near- stoichiometric quantities of curative to achieve maximum physical properties. As with other classes of thermoset polymer materials, blending different grades of epoxy resin, as well as use of additives, plasticizers or fillers is common to achieve the desired processing or final properties, or to reduce cost. Use of blending, additives and fillers is often referred to as formulating. Bisphenol A epoxy resin. As the molecular weight of the resin increases, the epoxide content reduces and the material behaves more and more like a thermoplastic. Very high molecular weight polycondensates (ca. These resins do however contain hydroxyl groups throughout the backbone, which may also undergo other cross- linking reactions, e. Compared to DGEBA, bisphenol F epoxy resins have lower viscosity and a higher mean epoxy content per gramme, which (once cured) gives them increased chemical resistance. Novolac epoxy resin. These are highly viscous to solid resins with typical mean epoxide functionality of around 2 to 6. The high epoxide functionality of these resins forms a highly crosslinked polymer network displaying high temperature and chemical resistance, but low flexibility. Aliphatic epoxy resin. The resulting resins may be monofunctional (e. These resins typically display low viscosity at room temperature (1. Pa. s) and are often referred to as reactive diluents. They are rarely used alone, but are rather employed to modify (reduce) the viscosity of other epoxy resins. This has led to the term . A related class is cycloaliphatic epoxy resin, which contains one or more cycloaliphatic rings in the molecule (e. This class also displays low viscosity at room temperature, but offers significantly higher temperature resistance than the aliphatic epoxy diluents. However, reactivity is rather low compared to other classes of epoxy resin, and high temperature curing using suitable accelerators is normally required. Glycidylamine epoxy resin. Important industrial grades are triglycidyl- p- aminophenol (functionality 3) and N,N',N'',N'''- tetraglycidyl- bis- (4- aminophenyl)- methan (functionality 4). The resins are low to medium viscosity at room temperature, which makes them easier to process than EPN or ECN resins. This coupled with high reactivity, plus high temperature resistance and mechanical properties of the resulting cured network makes them important materials for aerospace composite applications. Curing epoxy resins. However, good properties are obtained by reacting the linear epoxy resin with suitable curatives to form three- dimensional cross- linked thermoset structures. This process is commonly referred to as curing or gelation process. In principle, any molecule containing a reactive hydrogen may react with the epoxide groups of the epoxy resin. Common classes of hardeners for epoxy resins include amines, acids, acid anhydrides, phenols, alcohols and thiols. Relative reactivity (lowest first) is approximately in the order: phenol < anhydride < aromatic amine < cycloaliphatic amine < aliphatic amine < thiol. Whilst some epoxy resin/ hardener combinations will cure at ambient temperature, many require heat, with temperatures up to 1. Insufficient heat during cure will result in a network with incomplete polymerisation, and thus reduced mechanical, chemical and heat resistance. Cure temperature should typically attain the glass transition temperature (Tg) of the fully cured network in order to achieve maximum properties. Temperature is sometimes increased in a step- wise fashion to control the rate of curing and prevent excessive heat build- up from the exothermic reaction. Hardeners which show only low or limited reactivity at ambient temperature, but which react with epoxy resins at elevated temperature are referred to as latent hardeners. When using latent hardeners, the epoxy resin and hardener may be mixed and stored for some time prior to use, which is advantageous for many industrial processes. Very latent hardeners enable one- component (1. K) products to be produced, whereby the resin and hardener are supplied pre- mixed to the end user and only require heat to initiate curing. One- component products generally have shorter shelf- lives than standard 2- component systems, and products may require cooled storage and transport. The epoxy curing reaction may be accelerated by addition of small quantities of accelerators. Tertiary amines, carboxylic acids and alcohols (especially phenols) are effective accelerators. Bisphenol A is a highly effective and widely used accelerator, but is now increasingly replaced due to health concerns with this substance. Homopolymerisation. This process is known as catalytic homopolymerisation. The resulting network contains only ether bridges, and exhibits high thermal and chemical resistance, but is brittle and often requires elevated temperature to effect curing, so finds only niche applications industrially. Epoxy homopolymerisation is often used when there is a requirement for UV curing, since cationic UV catalysts may be employed (e. Primary amines undergo an addition reaction with the epoxide group to form a hydroxyl group and a secondary amine. The secondary amine can further react with an epoxide to form a tertiary amine and an additional hydroxyl group. Kinetic studies have shown the reactivity of the primary amine to be approximately double that of the secondary amine. Use of a difunctional or polyfunctional amine forms a three- dimensional cross- linked network. Aliphatic, cycloaliphatic and aromatic amines are all employed as epoxy hardeners. Amine type will alter both the processing properties (viscosity, reactivity) and the final properties (mechanical, temperature and heat resistance) of the cured copolymer network. Thus amine structure is normally selected according to the application. Reactivity is broadly in the order aliphatic amines > cycloaliphatic amines > aromatic amines. Temperature resistance generally increases in the same order, since aromatic amines form much more rigid structures than aliphatic amines. Whilst aromatic amines were once widely used as epoxy resin hardeners due to the excellent end properties they imparted, health concerns with handling these materials means that they have now largely been replaced by safer aliphatic or cycloaliphatic alternatives. The amine (NH2) groups react with the epoxide groups of the resin during polymerisation. Anhydrides. Reaction occurs only after opening of the anhydride ring, e. A possible side reaction may also occur between the epoxide and hydroxyl groups, but this may suppressed by addition of tertiary amines. The low viscosity and high latency of anhydride hardeners makes them suitable for processing systems which require addition of mineral fillers prior to curing, e. The resulting material has ether linkages and displays higher chemical and oxidation resistance than typically obtained by curing with amines or anhydrides. Since many novolacs are solids, this class of hardeners is often employed for powder coatings. Also known as mercaptans, thiols contain a sulfur which reacts very readily with the epoxide group, even at ambient or sub- ambient temperatures. Whilst the resulting network does not typically display high temperature or chemical resistance, the high reactivity of the thiol group makes it useful for applications where heated curing is not possible, or very fast cure is required e. Thiols have a characteristic odour, which can be detected in many two- component household adhesives. History. Pierre Castan. Castan's work was licensed by Ciba, Ltd. Independent publisher of first- class, popular non- fiction.
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